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This incredible list comes from Two Thirds Unschooling. Thank You:) I've also added some from Faith's comments.
Early Learning:
1. Starfall - Teaches alphabet and early reading skills.
starfall.com
2. Brightly Beaming Resources - Letter of the week, sound of the week, science of the week, etc. This is a good all-around site for early learning.
http://www.letteroftheweek.com/
3. Rhyme a week
http://curry.edschool.virginia.edu/g....htm#This_Week
4. Enchanted Learning - Not really free, but a lot can be accessed without paying (membership is $20 donation/year per family)
http://www.enchantedlearning.com/Home.html
Whole Curriculum:
1. Ambleside Online - Charlotte Mason. Wonderful resource that includes lots of info and is really a full curriculum option. Great booklist!
http://amblesideonline.org/index.shtml
2. An Old-Fashioned Education - Another really complete option. LOTS of stuff to look at and use here!
http://oldfashionededucation.com/
3. Puritans' Home School - I have heard good things, but have never used this. VERY religious site, but it does appear pretty complete.
http://www.puritans.net/curriculum/
4. Core Knowledge lesson plans - Tons of lesson plans on lots of subjects from PK-8. I have not used this, but it looks really good.
http://www.coreknowledge.org/CK/resr...sons/index.htm
5. About.com Homeschooling section (not really a whole curriculum, but TONS of stuff)
http://homeschooling.about.com/
Math:
1. Ray's Arithmetic - 1885 math book on google books. Thorough and "back to basics". (click on the icon on the page and scroll down to read/print)
http://books.google.com/books?id=eop...age&q=&f=false
3. First Lessons in Arithmetic - 1878 math text
http://www.donpotter.net/math.htm
4. NC public school math program K-2
http://community.learnnc.org/dpi/mat...s_k2_resou.php
5. Centre for Innovation in Mathematics Teaching (UK) - AKA MEP
http://www.cimt.plymouth.ac.uk/projects/mep/default.htm
6. Living Math History (lessons on right)
http://livingmath.net/LessonPlans/C1...S/Default.aspx
7. Pearson Scott Foresman K-5
http://pgcounty.scottforesman.com/
8. Geogebra (Algebra and Geometry)
http://www.geogebra.org/cms/
9. Oakes Math
http://dorioakes.bravehost.com/Math.html
10. Eduplace printable workbooks
http://www.eduplace.com/math/hmm/practice/lp_1.html
http://www.eduplace.com/math/hmm/practice/lp_2.html
http://www.eduplace.com/math/hmm/practice/lp_3.html
http://www.eduplace.com/math/hmm/practice/l _ 4.html http://www.eduplace.com/math/hmm/practice/lp_5.html
http://www.eduplace.com/math/hmm/practice/lp_6.html
and activities that coordinate with this program
http://www.eduplace.com/kids/hmm/
11. Middle/High school math
http://go.hrw.com/gopages/ma-msm.html
6. Society for Quality Education
http://www.societyforqualityeducatio...stairway2.html
Literature/Reading Guides and Units:
1. Novel Study Guides for the Classroom Teacher
http://www.nt.net/~torino/novels3.html
2. Reading Units by Gay Miller
http://www.mce.k12tn.net/units/units_with_books.htm
3. Garden of Praise
http://www.gardenofpraise.com/lesson.htm
4. Glencoe Literature Guides
http://www.glencoe.com/sec/literature/litlibrary/
5. Literature Activity Guides by Nancy Polette - These are samples, but are in depth enough to test if your child understood the story.
http://www.nancypolette.com/litguides.asp
17. Charlotte Mason stuff (not all free)
http://simplycharlottemason.com/
18. FossWeb by Delta Education. Click on the subject, then teacher resources. You will then have to click on Teacher Prep videos for the lessons. Everything else on the page supports the lessons. There are games, worksheets, and many additional resources listed
http://www.fossweb.com/modules3-6/index.html
19. Higher Up and Further In blog
http://higherupandfurtherin.blogspot.com/
20. Pioneer Woman blog
http://thepioneerwoman.com/
21. Well-Trained Mind
welltrainedmind.com/forums/
22. Teacher Tube
http://www.teachertube.com/
Science:
1. Engineering for kids ages 8 and up. Single subject lesson plans. Nicely done and easy to understand
http://www.welltrainedmind.com/forum...ree+curriculum
2. Earth Awareness Curriculum for Middle Schoolers
http://cygnus-group.com/use-less-stuff/NSTA.html
3. Life Science Curriculum
http://www.eequalsmcq.com/Thank%20yo...%20Science.htm
18. BODIES, the exhibition ~ includes educator guides for various grade levels from Carnegie Science Center. Even if you aren't interested in the exhibit or pictures of the preserved bodies, there is good info in the guides that can be used for lessons:
http://wheresciencehappens.org/bodiesguide.htm
Computer Science:
1. Blender 3D animation creation
http://www.blender.org/
12. Mommy Teach Me Spanish
http://www.youtube.com/results?searc...rch_type=&aq=f
13. In the Beginning Greek
http://www.inthebeginning.org/
Home Economics/Life Skills:
1. Future Christian Homemakers
http://www.futurechristianhomemakers...sonsIndex.html
Virtual Field Trips:
1. Take a field Trip
http://www.uen.org/tours/fieldtrips2.shtml
2. Meet Me at the Corner
http://www.meetmeatthecorner.org/
High School/College :
1. HippoCampus Free Courses
http://www.hippocampus.org/
2. Mixed Courses in many subjects
http://www.free-ed.net/free-ed/
3. Printable Courses in all subject areas. Not sure who funds this one, but I like how the curriculum is laid out
http://www.pass.leon.k12.fl.us/Speci...t%20Areas.aspx
4. University of Berkley Courses. Tons of Free Courses available here
http://webcast.berkeley.edu/
5. Yale University Open Courses. Nicely done and easy to access IMO
http://oyc.yale.edu/
6. University of Washington free courses
http://www.outreach.washington.edu/openuw/
7. M.I.T. open Courseware. Tons of completely free courses in many subjects
http://ocw.mit.edu/OcwWeb/web/courses/courses/index.htm